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Anonymous

Guest
but how is cyanide manufacture and trade monitored around the world, or in the u.s., if at all ?

any good links known for guidlines to handling/production of hazardous materials, ?
 
A

Anonymous

Guest
Here ya go Vitz, this is one of many found here http://www.osha.gov/pls/oshaweb/owasrch ... p_logger=1

General Description
Synonyms: Potassium cyanide; Sodium cyanide

OSHA IMIS Code Number: 0790

Chemical Abstracts Service (CAS) Registry Number: 57-12-5

Other Related Chemical Abstracts Service (CAS) Registry Numbers: 74-90-8; 592-01-8; 151-50-8; 143-33-9

Related Chemical:
Hydrogen Cyanide
Exposure Limits
OSHA Permissible Exposure Limit (PEL) for General Industry: 29 CFR 1910.1000 Z-1 Table -- 5 mg/m3 TWA; Skin

OSHA Permissible Exposure Limit (PEL) for Maritime: 29 CFR 1915.1000 Table Z-Shipyards -- 5 mg/m3 TWA

American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value (TLV): HCN - 4.7 ppm, 5 mg/m3 Ceiling; Skin -- Cyanide salts (CaCN, KCN, NaCN) - 5 mg/m3 Ceiling; Skin

National Institute for Occupational Safety and Health (NIOSH) Recommended Exposure Limit (REL): HCN - 4.7 ppm, 5 mg/m3 STEL; Skin -- Other Cyanides (as CN) except HCN - 4.7 ppm, 5 mg/m3 Ceiling (10 Minutes)
Health Factors
Environmental Protection Agency (EPA) carcinogenic classification: Group D, not classifiable as to human carcinogenicity

NIOSH Immediately Dangerous To Life or Health Concentration (IDLH): 25 mg/m3 (as CN)

Potential symptoms: Asphyxia and death can occur, preceded by seizures, coma with abolished deep reflexes and dilated pupils, weakness; paralysis; dizziness; numbness; anxiety; chest tightness; irregular heartbeat; shortness of breath; confusion; headache; sore throat; nausea, vomiting; eye irritation; rash, chemical burns on skin; enlargement of thyroid gland.

Health Effects: Irritation-Eyes, Skin, Nose, Throat---Marked (HE14); Acute Toxicity (HE4).

Affected organs: cardiovascular system, respiratory system, thyroid, eyes, skin, blood

Note: Neurological sequelae in survivors of acute cyanide poisoning include parkinsonism and dystonia.

Date Last Revised: 07/15/2003

Literature Basis:
(symptoms)
Agency for Toxic Substances and Disease Registry (ATSDR): Toxicological Profile for Cyanide (Update). PHS, U.S. DHHS, Atlanta, GA, 1997.
International Chemical Safety Cards (WHO/IPCS/ILO): Potassium cyanide.
International Chemical Safety Cards (WHO/IPCS/ILO): Sodium cyanide.
U.S. EPA Technology Transfer Network Air Toxics Website: Cyanide Compounds.
(target organs, IDLH)
NIOSH Pocket Guide to Chemical Hazards: Potassium cyanide.
NIOSH Pocket Guide to Chemical Hazards: Sodium cyanide.
(neurological sequelae)
Albin, R.L.: Basal ganglia neurotoxins. Neurol. Clin. 18(3): 665-680, 2000
Monitoring Methods used by OSHA
Laboratory Sampling/Analytical Method:

sampling media: Mixed Cellulose Ester Filter (MCEF) 0.8 microns in series with Midget Fritted Glass Bubbler (MFGB) containing 10 mL 0.1 N NaOH
maximum volume: 120 Liters maximum flow rate: 1.0 L/min
current analytical method: Ion Specific Electrode; ISE
method reference: OSHA Manual of Analytical Methods (OSHA ID-120)
method classification: Fully Validated
note: Submit as a separate sample. If present, sulfide should be listed as an interference. Particulate cyanide is collected on the filter. HCN, if present, is collected in the Midger Fritted Glass Bubbler. (See HCN) Within 1 hour after the sample has been collected, transfer the filter to a clean screw cap vial.

On-Site Sampling Techniques/Methods:

device: Detector Tube
manufacturer: Dräger
model/type: Cyanide 2/a, order no. 67 28791
sampling information: 10 strokes
upper measurement limit: 15 mg/m3
detection limit: approximately 1 mg/m3
overall uncertainty: 33-49%
method reference: on-site air secondary (manufacturer)

Wipe sampling: Whatman smear tab; Solvent: Deionized Water
* All Trademarks are the property of their respective owners.

Revised: 29 September 2003
 

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