I have my RO/DI unit feeding into a rubbermaid garbage can, hooked up to the float valve that was posted above. The RO/DI unit I have has an auto shut off, that turns the unit off when pressure builds up behind a closed float valve. This allow me to turn the unit on and walk away from it, not worrying that it will overfill the garbage can and spill water all over the place. When the garbage can is filled, I manually turn off the RO/DI so that it will not continually replace the water that is used to top off my tank.
I have the same float switch recommended above, and that is hooked up to a small pump with hose leading to my sump. When the fresh water reservior runs low, I manually turn on the RO/DI and fill it back up again, usually overnight, and then turn it off again the next morning.
Worst case scenario, if the float switch failed and pumped the entire contents of my water reservoir, it would only dump about 30 gallons into my system (which is about 10% of my entire water volume).