if the heater wasn't on, then no, since the metals are inert and would need to oxidize over time (rust), but if the thermostat turn on, you could have electroplating (can't remember the word for this). If your home circuit breaker didn't trip, the thermostat probably didn't turn on at all. Of course I'm not familiar with that heaters circuitry, but it probably has some sort of safety switch in case water leaks in.