My next option is using a bubbler with a air stone in the sump and see if that works. I was thinking of putting the bubbler intake line outside
Yes, that will help. What i like from u , is....when u ask for help, u come w/most Hard Problem.
Back to OP, dog may be 5% CO2 problem (u just make buy a CO2 meter.lol)
Dosing (in special Vinegar) may be to early for this tank , this is the 180 gal. just setup few months back ? I i will C/P this from one link i pot to u.
"The aquarium is still cycling, and has excess acid being produced from the nitrogen cycle and degradation of organics to CO2."