A lot of times the room that the tank in doesn't have good air circulation, which can result in a lot of CO2 in the air, which can make the Ph low. You want to make sure you get enough air into the room, opening a window does help. The Skimmer will suck in air, so if the room doesn't have good air circulation the skimmer will be sucking in that air. You also want to make sure you have good water breakage, as that will help remove the CO2 from the water.
It dropping at night to 7.8 isn't that big of a worry, and is very common.