I would think that any fish that lays eggs would eventually have spawn that would be released into the water column. I have yellow tail damsels that frequently breed and I have watched the eggs hatch once (frye are about the size of baby brine shrimp) and have watched everything in the tank go crazy (including the corals, which are huge the next morning). On top of this, I have 2 cleaner shrimp which also regularly spawn (I am thinking one of them might do so tonight). These will periodically add food to the water column, but I wouldn't rely on this as a consistent food, more of a treat once in a while. Any of the fish that breed readily in the tank will accomplish what you are thinking of, as well as many inverts (clowns, damsels, etc. will bread readily, as will most shrimp).