Catching fish out of a reef is really no big deal, despite what you may read to the contrary. In 10 minutes I caught an anthias out of tank that the owner had been trying to catch for a year.
Method 1. Wait until dark. Feed you fish, and wait until the fish you are after is near the surface, have a net ready. When the fish is in good position turn off the tank lights, or have someone else do it for you. Scoop the net where the fish was when you turned the light out. Or, alternatively, use a flash light after the light is out to spot him first, but I've never found this to be necessary.
Method 2. Put the net in the tank, let the fish acclimate to it, and wait for your target fish to just swim into it. It may take a day or two, but it works.
Method 3. Hook and line. Relaible, but least desireable as it can injure the fish.
I've used all of these methods with great success.
Ich will not harm corals, but your fish are in danger if indeed this is ich. You can feed garlic or medicated food as kind of a preventative measure for your other fish.
Jim