hi.
First of all, I want to say that I may not agree with some of you regarding AC/chiller choice, depends on setup.
As I said already, the heat capacity of air is so small that it will take 500X more energy to cool air than same amount of water. So assume the heat exchange between the air and water is perfect (nothing in practical thermodynamic is perfect, but let's say that the surface area of the bubble is infinite, and the heat transfer between air bubble and the tank water is perfect), then it will take 500 gal of 0F dry air to cool 1 gal of tank water from 80F to 40F. Or the same amount of air to cool 8 gal of water to 75F.
Now, do you know how many gal of air does your skimmer suck in per day? For non-commerical skimmer, it is about in the magnitude of gallon per hour. So compare to the size of you tank, the amount of cooling in a perfect situation is almost negliectible.
On a lighter note, did anybody heard about the myth of a newbie reefer who don't want to buy a water heater, and use a hair dryer blowing hot air at water surface to keep his/her tank warm during the winter? Now hair dryer will do a better job in heating up tank water than chilly air from outside, so please don't laugh at this.
Now regarding the AC/Chiller issue. If the chiller is remotely mounted, meaning that the hot air from chiller is direct outside instead of recirculated within the room, then a chiller will be more efficient in cooling a tank than a room AC. If the reefer want to enjoy comfortable room temperature while in the room, then it maybe a good investiment to get a room AC instead of chiller alone. This assumes that the "value" of the comfort is more than the extra energy that a room AC uses. Extra energy will needed because of the inefficiency of heat transfer between room air and the tank water, as well as heat gain due to opening door/window and heat transfer thru house wall and others.
Another exception is if the chiller can not be setup in such a way that the heat can be transfer away from the room's air. This is like running a portable AC in the middle of a room, with cool air coming from one side, and hot air coming from the opposite side, essentially cancel out the cooling affect while adding more net heat to the room. For chiller, this is not so bad, because the tank wall insolated the water from the air a little. See the hair dryer myth above. So it is not so bad as some people feel.
Other issue is that when sizing a room AC, you have to consider the extra heat from the tank. An room AC work for a normal 200 sqft living room will not work on a fish room of the same size with 13 240 gal tanks, for example. All in all, there are so many issues that it is impossible to give fool-proof recommendation without knowing the preference of the reefer and other constraints.