There are a couple of problems that I can think of with natural sunlight off the top of my head. First, there would probably be quite a bit of heat generated on such a small system. Second, the days are much shorter this far north than they are in the equatorial places that most tropical corals come from. Third, sunlight is full spectrum, meaning that the warmer red and yellow light (filtered out by several feet of water in nature and not introduce because of 6500K or cooler bulbs in captivity,) would penetrate the tank. Most algae likes the warmer red and yellow light, and would probably thrive in a shallow tank lit exclusively by natural means. :evil: It would probably be a constant, loosing, battle. In a temperature controlled room, natural sunlight can be a neat way to enjoy and spotlight some of your tanks, but I think that in such a small system, it should be limited to a neat accent.
Mike