Ditto. I would not bother with pH value in ultrapure water. It is does not make any use. The conductivity and other electrochemical properties is *specifically* derived to measure ultrapure water, and this is why you can get good measurement with the technique. With CO2 purging, you can get the conductivity of water down to 0.05 uS/cm. pH is related to dynamic of the chemical potential of the H+ ion. Since there are very few ion in the ultrapure water, the instrument will give you result that does not make sense.
BTW, "pure" water has pH of 7 under very specific conditions (temp for example). That assume there is enough ions in there for the measurement. It is very unlikely that one get 7.0 pH. If you buy a calibration fluid for pH meter, they don't give you "pure" water for a reason even if you get one at pH of 7. It is usually buffered with chemicals, for example.