If I remember correctly, both are mixed as a way to lessen the increase of sulfate and chloride counter ions.
According to Randy's Diy article, MgSO4 supp's have the potential to quickly increased levels of SO4.
MgCl2 supp's can also lead to increased levels of Chloride anion, but its increase is negligible to already prexisting high levels of Cl- in seawater.