Soda ash has a very high pH around 11 and no buffering.
I use to make this stuff up by baking baking soda in the oven or in a pan for a minute or 2, until the powder boiled and flowed like water. Then I'd use it to get the pH up really fast back when I was breeding African cichlids. Not sure why you'd need it in a reef system, since adding it will break the buffering capacity of the pre mixed salt mixes.