In simplest terms, if your alk/calc/pH is in proper levels, the small amount of top off water with a low pH you add isnt going to make a difference. That is what the buffer system in your tank is for, to "eat up" any differences and keep the pH steady.
Alkalinity is the measurement of how much can be added without a pH swing.
Do not add any buffers to water you are mixing unless you are adding it immediately, as a precipitation event will take place if it sits.
Using b-ionic alk/calc is the best product I have ever used. In the summer months, when I am adding a lot of top off water, I am using the duo in larger amounts to stabilize my low pH top off water. In the winter, I don't use as much, and my water changes keep the lvels pretty consistent.