OK here's the deal on the east river....
it is Saltwater, not brackish, I've taken salinty measurements ranged anywhere from 1.021-1.023 depending on temperature.
all of the storm sewers (ones you see on corners) empty into the east river or hudson river, this will effect saliniity if you take it after a rain storm.
the east river is getting better evidence is the return of "ship Worms" whicjh bore into the submerged pilings. I can say from expierence that east river is the cleanest of the surrounding rivers harlem, hudson and bronx river and westchester creek.
there is a tremendous amount of water flow in the east river which constantly brings in ocean life, late july early august there is a ton of tropical fish that come up with the Gulf stream, I have caught alantic Blue tangs ( yellow in juvey stage) queen angels, blue angels, four eye butterflys, file fish, grey angel, french angel, pipe fish.
great spot to get them is under the wall street heliport, there is a barge on pilings making the outer leg of the heliport, there is an ab undance of anenome, sponge, algae etc, they tend to hide in this artifical reef.
definity not the place to dive though, heavy current, lots of boat traffic and is a frequently dove area by the NYPD SCUBA team due to the threat of terrorism.
the fish I've collected through the years has had a low survival rate, not because of the water quality but IMHO the fish are well stressed from the 2000 mile+ ride and just simply cant adapt. the largest angel I caught was 3/4" long.
The SCUBA team has a 14-15" bumble bee grouper in a 180 (when they got it , it was 1.5") they readily feed it glass shrimp, and worms they catch right outside in slip.
I personally prefer not to go throught the hassle of collecting food, much easier to just hit LFS and buy it