Hi reefers,
I'm glad that I'm not the only one constantly mind buggled with issues such as maintaining Ca2+ level and dropping PO4. I'm intermediate aquarist always trying some random stuff and I thought this may clarify few ideas written in this tread. I have no intension to offend anyone!!!
http://www.aquacare.de/info/tipps/e1kalkwa.htm#Welche%20Art
My rule of thum with reefkeeping is not to go cheap, cause it comes back as Karma!!! so adding Calcium reactor is ++++ that I recommend to reefers!!!
Here is great website that explain how Calcium reactor works and how Kalkwasser works! so read it here!!!
"
You can hear very often that
"Kalkwasser" and
Chalk Reactor are not working together very well. The only problems you can get is that both outlets "Kalkwasser" and Chalk Reactors are dropping their water together at one point. At this point Calcium Carbonate will precipitate and the efficiency of both systems will drop. But if both outlets are fare away from each other or the systems will not work at the same time nothing will occur and you have the advantages from both systems:
First the CO2 in the aquarium water that is produced by every Chalk Reactor will be neutralized partial by the "Kalkwasser" (pH rising). Second the lack of buffer capacity (KH value) that will follow the "Kalkwasser" input will be compensated with a Chalk Reactor. With the combination of "Kalkwasser" and Chalk Reactor you can lower the daily pH oscillations: at night the "Kalkwasser" will compensate the falling pH and during the daytime the Chalk Reactor will reduce the rising of the pH. But therefore you need strong systems that are able to produce Calcium and KH within some hours per day.
It is possible, too, to combine Carbonate Hardness supplies (e.g.
KH-plus,
Triple Buffer), Calcium solutions (e.g.
Calcium-plus) and Magnesium solutions (e.g.
Magnesium-plus). These substances are very comfortable in small aquaria of if the installed systems (Chalk Reactor, "Kalkwasser" Reactor) are too weak. In some aquaria one of the both values calcium and KH are not in order. In that cases you can rise only this value with the care substances very easily. But for this methods the same rule: only use them separately. "
http://www.aquacare.de/info/tipps/e1kalkwa.htm#Welche Art
so here is the summary!
Calcium reactor works best around Ph 6.5-6.7 which is acidic (electron donor) Kalkwasser water is around 11-12 they say, I think we aquarist tend to supersaturate it so its probably >12, (electron acceptor) so we have two players that are willing to participate! one who is going to donate electron and the other thats willing to accept the electron! How do we keep in balance? dKH buffer is the fulcrum in the middle of the two that balances the seesaw of acid and base.
So in order to achieve/maintain Ca2+level 450ppm in closed system, you have to work your water parameters also. (I personally try to aim for around 410ppm calcium level, thats whats found in natural sea water @ 1.025ppm salinity, 74degrees, Theoretically speaking, I don't think 450ppm is even possible unless you shift the equalibrium oneway)
First, eveything is affected by temperature! in general rule of thumb enzyme reaction rate is doubled per 10degree/Celsius increase. It also affects Oxygen saturation level. Celcius converted to Ferenheight I used to think of the temp difference lightly, but I'm a firm believer now, especially in a reeftank, because we are dealing with trace elements in PPM(parts per million).
Temperature affects Salinity! and Salinity affects the solubility of Calcium along with other inorganics. Amount of trace elements, i.e Magnesium plays key role in keeping up with Calcium! So its does play a role, I tend to just follow the manufacture's instruction and not test it!
Kalkwasser reactors are great, but I personally don't think they are worth the money!!!($300-500) especially whey they come with maxi jet pump!!! horrible design!
I recommend DIY Kalkwasser reactor! the idea is to constantly stirr the kalkwasser in a closed container to prevent limewater from reacting with CO2 right? So get a 5gal salt water bucket, and put a lid! If you want to get fancy, go to ebay, type in magnetic stirrer and buy a cheap stirrer! ($10-30) along with magnetic bar! there you got yourself a kalk reactor! You can even put a float valve inside a bucket, and a nipple that connects to the sump float valve to replenish evap water!!!!
How to raise dKH? use your ARM, I mean Arm & Hammer Baking Soda, its cheap, (almost pharmaceutical grade)...FDA & Hospital approved. So save your money !!!!
I strongly recommend Kalkwasser use because it also lowers PO4 level;
Calcium reacts with phosphate to yield Ca3(PO4)3, which is harmless.
I hope this clarified some misconceptions!!!
Calcium reactor
Kalwasser
Buffer
all three components works well separately, but they can be used together to produce optimum results!
Happy reefing!!!!